研究方向: 1. 过渡金属催化的有机和金属有机反应的反应机理的研究。 研究经历: 1998.7-2004.11 天津大学化学系 助教、讲师 研究项目: 1.亚胺和一氧化碳交替共聚反应合成多肽类高分子材料 (项目主要参与人),国家自然科学基金重点项目, 2009-2012年 (20834002),项目负责人为孙怀林教授。
已结题项目: 1. 过渡金属催化的碳-碳偶联反应的理论研究(项目负责人),天津市应用基础研究计划项目, 2007-2009,(06YFJMJC15200) 2. 金催化的一系列有机反应机理的理论研究(项目负责人),国家自然科学基金, 2008-2010年。 3. 新型含硼氮杂环的卡宾类似物参与的有机反应机理的理论研究(项目负责人),国家自然科学基金, 2009-2011年 (20872109)。
2012年计划招“有机化学”研究生1名,从事国家基金的研究。也欢迎本科生来本实验室从事毕业论文或创新实验研究。 组内学生就业去向:
*为保护个人隐私,未给出具体公司名称,有问题欢迎来信咨询。
代表论文 (文章列表及引用请看我的ResearcherID Profile): 14. Bowen Liu, Min Gao, Li Dang, Haitao Zhao,* Todd B. Marder* and Zhenyang Lin*, "DFT Studies on the Mechanisms of the Platinum-Catalyzed Diboration of Acyclic α,β-Unsaturated Carbonyl Compounds" Organometallics , 31, 3410-3425 ( 2012 ) Link 13. Guozhi Fan, Haitao Zhao, Zhenxiao Duan, Tao Fang,Minghai Wan and Liangnian He, "A novel method to synthesize diphenyl carbonate from carbon dioxide and phenol in the presence of methanol", Catalysis Science & Technology, 7,1138-1141 (2011) Link 12. Xin Zhang,Haitao Zhao*, Jianhui Wang*," A Recyclable Au(I) Catalyst for Selective Homocoupling of Arylboronic Acids: Significant Enhancement of Nano-Surface Binding for Stability and Catalytic Activity " , J. Nanosci. Nanotechno.,10,5153-5160 (2010)Link 11. Brant C. Boren, Sridhar Narayan, Lars K. Rasmussen, Li Zhang, Haitao Zhao,Zhenyang Lin, Guochen Jia and Valery V. Fokin "Ruthenium-Catalyzed Azide-Alkyne Cycloaddition: Scope and Mechanism" J. Am. Chem. Soc., 130, 8923-8930 (2008) Link 10. Haitao Zhao, Li Dang, Todd B. Marder and Zhenyang Lin "DFT Studies on the Mechanism of the Diboration of Aldehydes Catalyzed by Copper(I) Boryl Complexes" J. Am. Chem. Soc., 130, 5580-5594 (2008). Link 9. Li Dang, Haitao Zhao, Zhenyang Lin and Todd B. Marder "Understanding the Higher Reactivity of B2cat2 versus B2pin2 in Copper(I)-Catalyzed Alkene Diboration Reactions"Organometallics, 27, 1178-1186 (2008) Link 8. Li Dang, Haitao Zhao, Zhenyang Lin and Todd B. Marder "DFT Studies of Alkene Insertions into Cu-B Bonds in Copper(I) Boryl Complexes" Organometallics, 26, 2824-2832 (2007) Link 7. Haitao Zhao, Zhenyang Lin and Todd B. Marder, "DFT Studies on the Mechanism of the Reduction of CO2 to CO Catalyzed by Copper(I) Boryl Complexes", J. Amer. Chem. Soc. 128, 15637-15643 (2006) , Link. 6. Yi Sun, Hoi-Shan Chan, Haitao Zhao, Zhenyang Lin, Zuowei Xie, "Ruthenium-Mediated Coupling/Cycloaddition of the Cyclopentadienyl Ligand in [{η5:σ-Me2C(C5H4)(C2B10H10)}Ru(NCCH3)2] with Alkynes", Angew. Chem. Int. Ed. 45 , 5533-5536 ( 2006 ) , Link 5. Haitao Zhao, Alireza Ariafard and Zhenyang Lin "In-depth Insight Into Metal-Alkene Bonding Interactions" Inorg. Chim. Acta, 359 , 3527-3534 ( 2006 ) Link 4. Haitao Zhao, Alireza Ariafard and Zhenyang Lin " bata -Heteroatom versus beta-Hydrogen Elimination: A Theoretical Study" Organometallics, 25 , 812-819 ( 2006 ) Link 3. Wenqin Zhang, Xiaorong Ran, Haitao Zhao and Lichang Wang "The nonmetallicity of molybdenum clusters" J. Chem. Phys. 121 , 7717-7724 ( 2004 ) Link 2. Haitao Zhao, Xiaofang Li, Xiaorong Ran and Wenqin Zhang "Theoretical study of reaction mechanism and regioselectivity of spiro-isoxazoline derivatives synthesized by intermolecular 1,3-dipolar cycloaddition" J. Mol. Struct. THEOCHEM 683 (1-3): 207-213 ( 2004 ) Link 1. Wenqin Zhang, Haitao Zhao and Lichang Wang "The simple cubic structure of ruthenium clusters" J. Phy. Chem. B 108 (7): 2140-2147 ( 2004 ) Link
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