李孝增

博士,教授,硕士及博士生导师

电话及传真: 022-27403475

E-mail: lixiaozeng321@tju.edu.cn

Professor Dr. Xiao-Zeng Li

Department of Chemistry,

Tianjin University,

Tianjin 300072,

P. R. China

于山东大学化学系获学士学位,于南开大学化学系获硕士学位博士学位。1990年起在天津大学化学系工作。---------------------

 

 

 

主要研究方向

1新型手性拆分剂的设计、合成、结构与应用研究

2功能材料配合物的设计、合成、结构、性质与应用研究

3)有机 - 无机杂化型超分子化合物的设计、合成、结构、性质与应用研究

4)精细化学品的制备、提纯、生产工艺改进及污染治理。

主要讲授课程:

Coordination chemistry ( 双语,研究生课程 ), 精细合成化学(本科生专业课), College chemistry ( 双语,本科生课程 )

部分论文:

·  Analysis of factors governing the formation of single-stranded helical coordination polymers from a macrocyclic metalloligand and Ca2+, Mn2+, Fe2+, Co2+, Ni2+, Cu2+, Zn2+ and Pb2+. CrystEngComm. 2013, 15, 2800.

 

·  Polynuclear complexes of a new macrocyclic oxamide metalloligand: Syntheses, crystal structures and deoxyribonucleic acid cleavage and magnetic properties. Inorganica Chimica Acta. 2013, 395, 197.

 

·  Syntheses and structures of eight-semi-coordinate M(II) (M=Mn, Fe, Co, Ni, Cu, Zn) complexes and density functional theory study of bond dissociation energies for the M-O semi coordinate bonds. Inorganic Chemistry Communications. 2013, 27, 114.

 

·  Synthesis, structures, and properties of new discrete hetero-tetranuclear metallocycle complexes based on macrocyclic oxamide metalloligands. Zeitschrift für anorganische und allgemeine Chemie. 2013, 639, 592.

 

·  New metalloligands suitable for the construction of polynuclear complexes and coordination polymers with exposed metal sites. CrystEngComm. 2012, 14, 366.

 

·  Syntheses, crystal structures and properties of lanthanide complexes featuring infinite molecular rectangle strands constructed from a new macrocyclic metalloligand. Inorganica Chimica Acta. 2012, 391, 20.

 

·  Two solvent directed zinc(II) coordination polymers with 1-D single-zigzag chain and 1-D double-zigzag chains. Journal of Coordination Chemistry. 2012, 4315.

 

·  Syntheses, structures, and properties of seven-coordinate calcium(II) and five-coordinate lead(II) complexes with 1-D structures. Journal of Coordination Chemistry. 2012, 3641.

 

·  A New Cationic Porphyrin Derivative (TMPipEOPP) with Large Side Arm Substituents: A Highly Selective G-Quadruplex Optical Probe. PloS ONE. 2012, 7,  DOI: 10.1371/journal.pone.0035586.

 

·  Syntheses and structures of two NiIICoIINiII complexes of macrocyclic ligands. Journal of Coordination Chemistry. 2011, 64, 3102.

 

·  A trigonal-prismatic Ag(I) complex and an octahedral Cu(II) complex incorporating with oxamide Ni(II) complex ligand: Syntheses, crystal structures and oxidative nuclease activities. Inorganica Chimica Acta. 2011, 375, 135.

 

·  DNA cleavage activities of tetraazamacrocyclic oxamido nickel(II) complexes. Polyhedron, 2010, 29, 574.  

·  Synthesis, crystal structure and DNA cleavage activity of a novel Ni(II)-Cd(II) coordination polymer. Inorg. Chim. Acta. 2009, 362, 1109.

·  From "naked" copper(II) ions and asymmetric macrocyclic complex linkers with a monodentate top and a bidentate top to molecular rectangle and infinite molecular rectangle strands. Inorg. Chim. Acta. 2008, 361, 1469.

·  Synthesis, structure and DNA cleavage activity of two 4,4'-dimethyl-2,2'-bipyridyl manganese(II) complexes. Inorg. Chim. Acta. 2008, 361, 29.

·  Oxidative DNA cleavage by Schiff base tetraazamacrocyclic oxamido nickel(II) complexes. J. Inorg. Biochem., 2008, 102, 824.

·  A new NiIICuIICuIINiII complex containing doubly end-on azido bridged dicopper(II) and macrocyclic nickel(II) complex ancillary ligands: Synthesis, structure and magnetism. Inorg. Chem. Commun., 2006, 9, 1297.

·  Appreciable Ni···O interactions at distances almost equal to the sum of the van der Waals radii of the two atoms. Inorg. Chem. Commun., 2005, 8, 939.

·  Synthesis and structure of a Ni(II )-Cu(II)-Ni(II) trinuclear complex with a new macrocyclic complex ligand. Acta Chim. Slovenia. 2005, 52, 332.

·  π ··· π interactions between a phenyl ring and four separate unclosed π-systems in the supramolecular structure of a new macrocyclic nickel(II) complex. Inorg. Chem. Commun., 2004, 7, 420.

·  Molecular and Supramolecular Structures of a Nickel(II) - Copper(II) - Nickel(II) Trinuclear Complex Containing a New Macrocyclic Oxamido Complex Ligand. Struct. Chem., 2004, 15, 547.

·  Intermolecular Interactions in the Crystal of a New Nickel(II)-cobalt(II)-nickel(II) Trinuclear Complex Containing a Macrocyclic Complex Ligand. Z. naturfor., 2004, 59b, 757.

·  Non-covalent interactions in the crystal of a new macrocyclic Ag(I)-Ni(II) binuclear complex. Acta Chim. Slovenia. 2004, 51, 343.

·  Structure and magnetism of a hydrogen-bond-linked three dimensional network of a novel Nickel(II)-Cobalt(II)-Nickel(II) complex containing a new macrocyclic mononuclear complex ligand. Trans. Met. Chem., 2003, 28(5), 506.

·  C-H ··· O, O-H ··· O and π ··· π interactions in the crystal structure of a new heterotrinuclear macrocyclic complex, [MnII (NiIIL)2 (C2H5OH)](ClO4)2 . Inorg. Chem. Commun., 2002, 5, 478.

·  Synthesis and supramolecular structure of a macrocyclic NiIICuIINiII trinuclear complex [CuII(NiIIL)2(CH3OH)2](ClO4)2 . J. Mol. Struct., 2002, 643, 135.

·  Crystal and molecular structure of a nickel(II) complex with a macrocyclic [14]N4 ligand. J. Chem . Crystallogr., 2003, 33(1), 5.

·  Synthesis and crystal structure of a binuclear zinc(II) complex of 2,6-diformylpyridine N-oxide bis(benzeoylhydrazone). Polyhedron. 1995,14(4), 511.

 

 

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